Movies
Bails N' Burns 1 of 2 ... Clear Classic mode.
Bails N' Burns 2 of 2 ... Achieve 100% completed in Story Mode.
Dev-Team Skates ... Achieve 100% completed in Classic Mode.
American Wasteland ... Clear Story Mode.

Characters
Clear Story Mode (Easy)
Robot Tony
Mindy

Clear Story Mode (Normal)
Little John
Iggy
Jason Ellis

Clear Story Mode (Hard/Sick)
Jimbo
Murphy
Mega

Clear Classic Mode (Normal)
Billie Joe
Boone

Clear Classic Mode (Sick/Hard)
Mat Hoffman
Dave

Achieve 100% in Classic Mode
Master Zen
Hardhat Guy
Downtown Guy
Grafitti Guy

Achieve 100% in Story Mode
Baller
Welder
Camera Guy
Chloe

Clear All Skate Ranch Missions
Barber
Carnival Guy
Downtown Guy
French Guy

Clear All Gaps
Oil Rig Guy
Policeman
Street Performer
Boone